Officers and NCOs:

Colonel - Matthew C. Butler (see notes)
Lieutenant Colonel - Frank Hampton
Major - Thomas E. Screven
Adjutant - Lt. James W. Moore
Surgeon - B. W. Taylor
Assistant Surgeon - Charles Davant,  Benjamin Walters Taylor
Assistant Commisary - S. B. Blocker
Chaplain - Manning Brown
Sergeant Major - C. H. Lanneau, Jr.
Bugler - William King

Enlisted Personnel and others:

J. H. Bessellier
W. A. Clarke
F. M. Davis
F. M. Drennon
P. A. Dudley
William Jennings
Milleage B. Johnson
John A. Lightsey
John C. Pender
E. R. Willis

Privates, 10; officers, 11; total, 21.

Source: South Carolina Troops in Confederate Service,

Notes:

Other research shows the Regiment was led by the following Field Officers:

Commander: COL Matthew C. Butler, COL Thomas J Lipscomb
Executive Officer: LTC William K Easley, LTC Frank Hampton, LTC Thomas J Lipscomb
Major: MAJ Thomas J Lipscomb, MAJ Thomas Screven